Inside the kitserver13 folder, run manager.exe as Administrator. Attach: Select pes2013.exe and click "Attach."
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If you are playing on a laptop with an Intel CPU and an Nvidia/AMD graphics card, PES 2013 likely defaults to the weak integrated Intel chip. You must manually force Windows to route the game through your high-performance card. For Nvidia Users: Inside the kitserver13 folder, run manager